FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2048446589> ?p ?o ?g. }

• W2048446589 endingPage "9763" @default.
• W2048446589 startingPage "9758" @default.
• W2048446589 abstract "We report here for the first time the application of atmospheric pressure photo ionization hydrogen/deuterium exchange (APPI HDX) coupled to high-resolution mass spectrometry for molecular level speciation of nitrogen containing compounds in crude oils. The speciation was done based on different combinations of ions produced from nitrogen containing compounds with various functional groups. To prove the concept, 20 nitrogen containing standard compounds were analyzed. As a result, it was shown that the nitrogen containing compound (M) with a primary amine functional group mainly produced a combination of [M – 2H + 2D]•+ and ([M – 2H + 2D] + D)+ ions, one with a secondary amine including alkylated or phenylated pyrrole a combination of [M – H + D]•+ and ([M – H + D] + D)+, one with a tertiary amine including N-alkylated or phenylated pyrrole a combination of [M]•+ and [M + D]+, and one with a pyridine functional group mostly [M + D]+ ions. The concept was successfully applied to do nitrogen speciation of resins fractions of two oil samples. Combined with the subsequent investigation of double bond equivalence distribution, it was shown that resins of Qinhuangdao crude oil sample contained mostly alkylated pyrrole and N-alkylated pyrrole type compounds but resins of shale oil extract contained mostly pyridine type nitrogen compounds. It was also shown that the speciation of individual elemental composition was also possible by use of this method. Overall, this study clearly shows that atmospheric pressure photo ionization hydrogen/deuterium exchange (APPI HDX) coupled to high-resolution mass spectrometry is a powerful analytical method to do nitrogen speciation of crude oil compounds at the molecular level." @default.
• W2048446589 created "2016-06-24" @default.
• W2048446589 creator A5052113779 @default.
• W2048446589 creator A5070402517 @default.
• W2048446589 date "2013-09-30" @default.
• W2048446589 modified "2023-10-16" @default.
• W2048446589 title "Application of Atmospheric Pressure Photo Ionization Hydrogen/Deuterium Exchange High-Resolution Mass Spectrometry for the Molecular Level Speciation of Nitrogen Compounds in Heavy Crude Oils" @default.
• W2048446589 cites W1791335410 @default.
• W2048446589 cites W1967002369 @default.
• W2048446589 cites W1982312446 @default.
• W2048446589 cites W1993167624 @default.
• W2048446589 cites W1994731507 @default.
• W2048446589 cites W1999922267 @default.
• W2048446589 cites W2003597195 @default.
• W2048446589 cites W2006399878 @default.
• W2048446589 cites W2009212043 @default.
• W2048446589 cites W2010272860 @default.
• W2048446589 cites W2013460689 @default.
• W2048446589 cites W2019374997 @default.
• W2048446589 cites W2023722951 @default.
• W2048446589 cites W2026700661 @default.
• W2048446589 cites W2027300379 @default.
• W2048446589 cites W2030830125 @default.
• W2048446589 cites W2041570745 @default.
• W2048446589 cites W2053680987 @default.
• W2048446589 cites W2059006176 @default.
• W2048446589 cites W2073323713 @default.
• W2048446589 cites W2073896201 @default.
• W2048446589 cites W2081077373 @default.
• W2048446589 cites W2084345312 @default.
• W2048446589 cites W2092839469 @default.
• W2048446589 cites W2096045876 @default.
• W2048446589 cites W2112413708 @default.
• W2048446589 cites W2121251778 @default.
• W2048446589 cites W2133822192 @default.
• W2048446589 cites W2313549426 @default.
• W2048446589 cites W2316964273 @default.
• W2048446589 cites W2318893345 @default.
• W2048446589 cites W2324177592 @default.
• W2048446589 cites W2327243445 @default.
• W2048446589 cites W2332742195 @default.
• W2048446589 cites W2333190322 @default.
• W2048446589 cites W2333275046 @default.
• W2048446589 cites W334914220 @default.
• W2048446589 doi "https://doi.org/10.1021/ac402157r" @default.
• W2048446589 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24033284" @default.
• W2048446589 hasPublicationYear "2013" @default.
• W2048446589 type Work @default.
• W2048446589 sameAs 2048446589 @default.
• W2048446589 citedByCount "55" @default.
• W2048446589 countsByYear W20484465892014 @default.
• W2048446589 countsByYear W20484465892015 @default.
• W2048446589 countsByYear W20484465892016 @default.
• W2048446589 countsByYear W20484465892017 @default.
• W2048446589 countsByYear W20484465892018 @default.
• W2048446589 countsByYear W20484465892019 @default.
• W2048446589 countsByYear W20484465892020 @default.
• W2048446589 countsByYear W20484465892021 @default.
• W2048446589 countsByYear W20484465892022 @default.
• W2048446589 countsByYear W20484465892023 @default.
• W2048446589 crossrefType "journal-article" @default.
• W2048446589 hasAuthorship W2048446589A5052113779 @default.
• W2048446589 hasAuthorship W2048446589A5070402517 @default.
• W2048446589 hasConcept C113196181 @default.
• W2048446589 hasConcept C162356407 @default.
• W2048446589 hasConcept C167569220 @default.
• W2048446589 hasConcept C178790620 @default.
• W2048446589 hasConcept C179104552 @default.
• W2048446589 hasConcept C185592680 @default.
• W2048446589 hasConcept C2779400197 @default.
• W2048446589 hasConcept C2779485729 @default.
• W2048446589 hasConcept C43617362 @default.
• W2048446589 hasConcept C537208039 @default.
• W2048446589 hasConceptScore W2048446589C113196181 @default.
• W2048446589 hasConceptScore W2048446589C162356407 @default.
• W2048446589 hasConceptScore W2048446589C167569220 @default.
• W2048446589 hasConceptScore W2048446589C178790620 @default.
• W2048446589 hasConceptScore W2048446589C179104552 @default.
• W2048446589 hasConceptScore W2048446589C185592680 @default.
• W2048446589 hasConceptScore W2048446589C2779400197 @default.
• W2048446589 hasConceptScore W2048446589C2779485729 @default.
• W2048446589 hasConceptScore W2048446589C43617362 @default.
• W2048446589 hasConceptScore W2048446589C537208039 @default.
• W2048446589 hasIssue "20" @default.
• W2048446589 hasLocation W20484465891 @default.
• W2048446589 hasLocation W20484465892 @default.
• W2048446589 hasOpenAccess W2048446589 @default.
• W2048446589 hasPrimaryLocation W20484465891 @default.
• W2048446589 hasRelatedWork W1976678501 @default.
• W2048446589 hasRelatedWork W2008449636 @default.
• W2048446589 hasRelatedWork W2010135690 @default.
• W2048446589 hasRelatedWork W2017146252 @default.
• W2048446589 hasRelatedWork W2082504247 @default.
• W2048446589 hasRelatedWork W2126251028 @default.
• W2048446589 hasRelatedWork W2148787175 @default.
• W2048446589 hasRelatedWork W2345446992 @default.
• W2048446589 hasRelatedWork W2952032444 @default.
• W2048446589 hasRelatedWork W2997339201 @default.

• next