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• W2048462930 abstract "The paramagnetic species on the surface of Al2O3MoO3CoO catalysts were studied. The ESR spectra of unsupported oxides CoO, Co2O3, Co3O4, CoAl2O4, and CoMoO4 were first studied. The ESR spectra of supported cobalt oxides were also studied. The spectra of supported oxides were different from those of the unsupported oxides, indicating that the supported cobalt ions are in a different state from those in unsupported oxides. The two-phase theory for the supported cobalt ions interprets the experimental results well. The Co2+ and Co3+ concentrations on the surface were estimated from ESR results. The desulfurization rate of Al2O3 MoO3CoO catalysts were measured together with the surface concentrations of Co2+, Co3+, Mo5+, and thionaphthol+O∗2− surface cation complex when H2 and thionaphthol were added to the surface. A simple correlation between the desulfurization rate and the concentrations of these paramagnetic species was found." @default.
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• W2048462930 date "1972-11-01" @default.
• W2048462930 modified "2023-10-16" @default.
• W2048462930 title "The paramagnetic species found on the surface of Al2O3$z.sbnd;MoO3$z.sbnd;CoO particles" @default.
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• W2048462930 doi "https://doi.org/10.1016/0021-9517(72)90269-2" @default.
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