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- W2048468056 abstract "X-ray crystallographic studies performed on the product of the ketalization reaction of 13β-ethyl-11α-hydroxy-gon-5-ene-3,17-dione have lead to the unequivocal assignment of the 10α stereochemistry to C10, showing that an inversion of configuration occurred during formation of the 3,17-diketal. From the Swern oxidation of this compound, 11α-(methylthio)methoxy-10α-gonene was obtained as the major product instead of the desired 11-ketone. Modeling studies showed that the configurational instability at C10 is determined by the presence of the 11α-hydroxyl group." @default.
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- W2048468056 date "2005-08-01" @default.
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- W2048468056 title "Crystal structures of 10α-gon-5-enes from the synthetic pathway to desogestrel" @default.
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- W2048468056 doi "https://doi.org/10.1016/j.steroids.2005.03.006" @default.
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