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- W2048470470 abstract "The self-assembly behavior and photo-responsive properties of novel azobenzene based copolymers poly(ethylene oxide) monomethyl ether-block-polystyrene-block-{poly[6-(4-methoxy-azobenzene-4′-oxy) hexylmethacrylate]}2 [MPEO-b-PS-b-(PMMAZO)2] with various block lengths of PMMAZO segments in aqueous media were studied by means of transmission electron microscopy (TEM), scanning electron microscopy (SEM), laser light scattering (LLS) and UV-Vis spectrophotometry. It was found that the critical water content for the aggregate formation increases with the PMMAZO weight fraction. By tailoring the molecular structure and copolymer concentration, various self-assembled aggregates were obtained. At a lower concentration, all the copolymers self-assembled into simple vesicles. With increasing the polymer concentration, large compound vesicles were formed. The photo-sensitive properties of the formed aggregates were also studied. Upon irradiation with a polarized light, the aggregates were elongated. Large compound vesicles were found to deform into compact spindles with a very large axial ratio." @default.
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- W2048470470 date "2012-01-01" @default.
- W2048470470 modified "2023-10-01" @default.
- W2048470470 title "Self-assembly and photo-responsive behavior of novel ABC2-type block copolymers containing azobenzene moieties" @default.
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- W2048470470 doi "https://doi.org/10.1039/c2sm07100b" @default.
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