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- W2048485770 abstract "Abstract The desulfurization of 1,3-bis(phenylthio)alk-1-enes with the low valent titanium species Cp 2 Ti[P(OEt) 3 ] 2 and subsequent reaction with tert -alkyl chlorides gave the terminal olefins regioselectively. The similar reactions also took place when β,γ-unsaturated thioacetals were treated successively with the titanocene(II) species and tert -alkyl chlorides. It was suggested that the present reactions proceeded via the formation of ( E )-vinyltitanium intermediate." @default.
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- W2048485770 date "1999-07-01" @default.
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- W2048485770 title "Titanocene(II)-promoted desulfurizative tertiary alkylation of 1,3-bis(phenylthio)alk-1-enes and β,γ-unsaturated thioacetals" @default.
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- W2048485770 doi "https://doi.org/10.1016/s0040-4039(99)00975-2" @default.
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