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- W2048498034 abstract "The rearrangement of 5-phenyl-1,1,1-trifluoro-2-(trifluoromethyl)pent-2-ene to 5-phenyl-1,1,1-trifluoro-2-(trifluoromethyl)pent-3-ene has been studied by 19F NMR in dimethylsulphoxide (DMSO). This isomerisation is catalysed by a base such as triethylamine. It is apparent that the olefin is more stable when the two trifluoromethyl groups are placed on a saturated carbon rather than on a vinylic carbon. In the isomerisation process, the part of triethylamine is to assist the intramolecular hydrogen transfer to give the more stable isomer." @default.
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- W2048498034 date "2001-10-01" @default.
- W2048498034 modified "2023-10-14" @default.
- W2048498034 title "Isomerisation reaction of a gem-bis-trifluoromethyl olefin in a basic medium: a kinetic study" @default.
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- W2048498034 doi "https://doi.org/10.1016/s0022-1139(01)00446-8" @default.
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