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- W2048502408 abstract "The equilibrium phase diagrams of Cu–Cr, Cu–Mo, and Cu–W show no measurable solid solubility except for a small solubility of Cr in solid Cu at higher temperatures. Even in the liquid state, the mutual solubilities in these systems are very limited. Simultaneous vapor deposition of elements on unheated substrates was used to produce alloy films covering the complete composition range of those three binary alloy systems. The films were characterized with the help of x-ray diffraction, transmission electron microscopy, and electron diffraction. In fcc Cu films, at least 10 at.% Cr, Mo, or W may be dissolved, whereas the bcc Cr, Mo, or W alloy films may accommodate at least 40 at.% Cu; the fcc and bcc solid solutions are separated by narrow two-phase fields. We further measured the composition dependence of the internal stress and of the electrical resistivity. Discontinuities in the measured curves generally coincide with the presence of phase boundaries in the (metastable) alloy films." @default.
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- W2048502408 date "1985-11-01" @default.
- W2048502408 modified "2023-09-24" @default.
- W2048502408 title "Metastable solid solutions in vapor deposited Cu–Cr, Cu–Mo, and Cu–W thin films" @default.
- W2048502408 doi "https://doi.org/10.1116/1.572799" @default.
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