Matches in SemOpenAlex for { <https://semopenalex.org/work/W2048503721> ?p ?o ?g. }
- W2048503721 endingPage "16758" @default.
- W2048503721 startingPage "16756" @default.
- W2048503721 abstract "The selective, direct hydrogenation of amides to the corresponding alcohols and amines with cleavage of the C−N bond was discovered. The expected products of C−O cleavage are not formed (except as traces in the case of anilides). The reaction proceeds under mild pressure and neutral, homogeneous conditions using a dearomatized, bipyridyl-based PNN Ru(II) pincer complex as a catalyst. The postulated mechanism involves metal−ligand cooperation by aromatization−dearomatization of the heteroaromatic pincer core and does not involve hydrolytic cleavage of the amide. The simplicity, generality, and efficiency of this environmentally benign process make it attractive for the direct transformations of amides to alcohols and amines in good to excellent yields." @default.
- W2048503721 created "2016-06-24" @default.
- W2048503721 creator A5022394866 @default.
- W2048503721 creator A5025119113 @default.
- W2048503721 creator A5025268103 @default.
- W2048503721 creator A5081692819 @default.
- W2048503721 date "2010-11-04" @default.
- W2048503721 modified "2023-10-05" @default.
- W2048503721 title "Direct Hydrogenation of Amides to Alcohols and Amines under Mild Conditions" @default.
- W2048503721 cites W1983107490 @default.
- W2048503721 cites W1991902977 @default.
- W2048503721 cites W1991971314 @default.
- W2048503721 cites W2009626516 @default.
- W2048503721 cites W2027301246 @default.
- W2048503721 cites W2027475453 @default.
- W2048503721 cites W2033383024 @default.
- W2048503721 cites W2033385316 @default.
- W2048503721 cites W2041912960 @default.
- W2048503721 cites W2049863329 @default.
- W2048503721 cites W2050592102 @default.
- W2048503721 cites W2072565033 @default.
- W2048503721 cites W2079415475 @default.
- W2048503721 cites W2089400651 @default.
- W2048503721 cites W2090574683 @default.
- W2048503721 cites W2095480759 @default.
- W2048503721 cites W2105128353 @default.
- W2048503721 cites W2107400648 @default.
- W2048503721 cites W2115476655 @default.
- W2048503721 cites W2116064503 @default.
- W2048503721 cites W2121091156 @default.
- W2048503721 cites W2158945597 @default.
- W2048503721 cites W2159458318 @default.
- W2048503721 cites W2167198311 @default.
- W2048503721 cites W2169170653 @default.
- W2048503721 cites W2327617832 @default.
- W2048503721 cites W2951023306 @default.
- W2048503721 doi "https://doi.org/10.1021/ja1080019" @default.
- W2048503721 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21049928" @default.
- W2048503721 hasPublicationYear "2010" @default.
- W2048503721 type Work @default.
- W2048503721 sameAs 2048503721 @default.
- W2048503721 citedByCount "382" @default.
- W2048503721 countsByYear W20485037212012 @default.
- W2048503721 countsByYear W20485037212013 @default.
- W2048503721 countsByYear W20485037212014 @default.
- W2048503721 countsByYear W20485037212015 @default.
- W2048503721 countsByYear W20485037212016 @default.
- W2048503721 countsByYear W20485037212017 @default.
- W2048503721 countsByYear W20485037212018 @default.
- W2048503721 countsByYear W20485037212019 @default.
- W2048503721 countsByYear W20485037212020 @default.
- W2048503721 countsByYear W20485037212021 @default.
- W2048503721 countsByYear W20485037212022 @default.
- W2048503721 countsByYear W20485037212023 @default.
- W2048503721 crossrefType "journal-article" @default.
- W2048503721 hasAuthorship W2048503721A5022394866 @default.
- W2048503721 hasAuthorship W2048503721A5025119113 @default.
- W2048503721 hasAuthorship W2048503721A5025268103 @default.
- W2048503721 hasAuthorship W2048503721A5081692819 @default.
- W2048503721 hasConcept C116569031 @default.
- W2048503721 hasConcept C121332964 @default.
- W2048503721 hasConcept C127413603 @default.
- W2048503721 hasConcept C161790260 @default.
- W2048503721 hasConcept C170493617 @default.
- W2048503721 hasConcept C175156509 @default.
- W2048503721 hasConcept C178790620 @default.
- W2048503721 hasConcept C185592680 @default.
- W2048503721 hasConcept C187320778 @default.
- W2048503721 hasConcept C21951064 @default.
- W2048503721 hasConcept C2778439535 @default.
- W2048503721 hasConcept C2779325354 @default.
- W2048503721 hasConcept C3044715 @default.
- W2048503721 hasConcept C43369102 @default.
- W2048503721 hasConcept C55493867 @default.
- W2048503721 hasConcept C66882249 @default.
- W2048503721 hasConcept C91819851 @default.
- W2048503721 hasConcept C94412978 @default.
- W2048503721 hasConcept C97355855 @default.
- W2048503721 hasConceptScore W2048503721C116569031 @default.
- W2048503721 hasConceptScore W2048503721C121332964 @default.
- W2048503721 hasConceptScore W2048503721C127413603 @default.
- W2048503721 hasConceptScore W2048503721C161790260 @default.
- W2048503721 hasConceptScore W2048503721C170493617 @default.
- W2048503721 hasConceptScore W2048503721C175156509 @default.
- W2048503721 hasConceptScore W2048503721C178790620 @default.
- W2048503721 hasConceptScore W2048503721C185592680 @default.
- W2048503721 hasConceptScore W2048503721C187320778 @default.
- W2048503721 hasConceptScore W2048503721C21951064 @default.
- W2048503721 hasConceptScore W2048503721C2778439535 @default.
- W2048503721 hasConceptScore W2048503721C2779325354 @default.
- W2048503721 hasConceptScore W2048503721C3044715 @default.
- W2048503721 hasConceptScore W2048503721C43369102 @default.
- W2048503721 hasConceptScore W2048503721C55493867 @default.
- W2048503721 hasConceptScore W2048503721C66882249 @default.
- W2048503721 hasConceptScore W2048503721C91819851 @default.
- W2048503721 hasConceptScore W2048503721C94412978 @default.
- W2048503721 hasConceptScore W2048503721C97355855 @default.
- W2048503721 hasIssue "47" @default.