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- W2048508514 abstract "The mechanism for the infrared intensity of the b1 C stretching mode of M(CO)5X complexes which was suggested recently by Kettle and Paul is discussed and amplified. It is shown that the band may derive part of its intensity from a cubic term in the dipole moment series expansion and part by «stealing» intensity from another hot band involving the a1(1) CO stretching mode. It would appear however that these mechanisms would be of less significance than distortion caused by the presence of unsymmetrical ligands." @default.
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- W2048508514 date "1968-03-01" @default.
- W2048508514 modified "2023-09-27" @default.
- W2048508514 title "The b1 CO stretching mode in the infrared spectra of C4v complexes of type M(CO)5X" @default.
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- W2048508514 doi "https://doi.org/10.1016/s0020-1693(00)87076-0" @default.
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