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- W2048520886 abstract "Pentacene derivatives substituted by aromatic groups at the 6,13-positions were prepared and investigated for their electronic properties and the photoaddition reaction with oxygen. The pentacene derivatives substituted by 2-thienyl and phenyl groups reacted with oxygen in solution under light and afforded their endoperoxides. These first-order kinetic constants were evaluated to be 1.5×10−3 s−1 and 2.7×10−3 s−1. The pentacene derivative with pentafluorophenyl groups was relatively stable in solution. The thermolysis and photolysis of the endoperoxide with 2-thienyl groups in solution afforded the pentacene derivative with yields of 30 and 44%, respectively. In addition, UV irradiation (254 nm) of the thin film of the endoperoxide was studied, which indicated the reproduction of the pentacene derivative." @default.
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- W2048520886 date "2007-09-01" @default.
- W2048520886 modified "2023-10-12" @default.
- W2048520886 title "Photooxidation and reproduction of pentacene derivatives substituted by aromatic groups" @default.
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- W2048520886 doi "https://doi.org/10.1016/j.tet.2007.07.021" @default.
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