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- W2048561215 abstract "Differential scanning calorimetry (DSC) studies of poly(ethylenetherephtalate) (PETP) film irradiated with high energy heavy ions at high ions fluencies are reported. Thin Mylar and Hostaphan PETP films (23 μm or 19 μm thick) were irradiated with Ar, Dy and Pb ions of the following energies and ions fluencies: Ar − 5.5 MeV/amu, 6 × 1011ions/cm2; Dy − 13 MeV/amu, 5 × 1010ions/cm2 and ca. 1011 ions/cm2; Pb − 11.4 MeV/amu, 1010 ions/cm2. DSC measurements were performed in nitrogen during heating-cooling-heating cycles at heating-cooling-heating rates of: 10-10-10°/min and 2-20-2°/min. Significant differences between pristine and the irradiated material were observed during melting and recrystallization processes occurring on primary heating, cooling and secondary heating. They have been attributed to film amorphization during heavy ion irradiation as a result of degradation and crosslinking, confirmed by gel permeation chromatography (GPC). The decrease in crystallinity and disappearance of long range order in the highly irradiated samples have been confirmed by wide and small angle X-ray scattering (WAXS, SAXS) results and density measurements. This can also be concluded on the basis of IR spectroscopy patterns. The DSC method can be applied in studies of structural changes occurring in thin polymer films after heavy ion irradiation." @default.
- W2048561215 created "2016-06-24" @default.
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- W2048561215 date "1995-11-01" @default.
- W2048561215 modified "2023-09-29" @default.
- W2048561215 title "Heavy ions track structure in a PETP" @default.
- W2048561215 cites W2019606049 @default.
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- W2048561215 doi "https://doi.org/10.1016/0168-583x(95)00822-5" @default.
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