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• W2048563669 abstract "The first experimental evidence for the formation of an organic tellurium-centered radical (RTe•, R = Ph or nBu groups) during the hydrotelluration of alkenes and alkynes is provided. The radicals were detected by electronic paramagnetic ressonance (EPR), using DBNBS (3,5-dibromo-4-nitrosobenzenesulfonate) as the spin trap. The radical adducts (DBNBS/•TenBu and DBNBS/•TePh) presented an EPR spectrum characterized by a triplet of triplets due to one nitrogen and two equivalent hydrogen atoms (aN = 21.6 G and aH = 0.7 G) and a g value of 2.0060. The presence of tellurium radical adducts was confirmed by isotopic substitution (125Te) and by electrospray and chemical ionization mass spectrometry and MS/MS analysis. The products showed isotopic patterns expected for compounds containing Br and Te. These results provide evidence for organic tellurium-centered radical formation and suggest that the hydrotelluration reactions occur by a free radical mechanism." @default.
• W2048563669 created "2016-06-24" @default.
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• W2048563669 date "2006-09-07" @default.
• W2048563669 modified "2023-09-30" @default.
• W2048563669 title "Organic Tellurium-Centered Radicals Evidenced by EPR Spin Trapping and Mass Spectrometry Experiments: Insights into the Mechanism of the Hydrotelluration Reaction" @default.
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• W2048563669 doi "https://doi.org/10.1021/om060560s" @default.
• W2048563669 hasPublicationYear "2006" @default.
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