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• W2048568926 startingPage "R9253" @default.
• W2048568926 abstract "Single crystals of ${mathrm{NdBa}}_{2}{mathrm{Cu}}_{3}{mathrm{O}}_{6+x}$ and ${mathrm{LaBa}}_{2}{mathrm{Cu}}_{3}{mathrm{O}}_{6+x}$ at oxygen concentrations $xensuremath{approx}0.4,$ 0.5, and 0.76 have been investigated by hard-x-ray diffraction. Intricate oxygen superstructures are found in nonsuperconducting ${mathrm{NdBa}}_{2}{mathrm{Cu}}_{3}{mathrm{O}}_{6.5}$ crystals. By numerical calculations we demonstrate that three unique coexisting oxygen configurations are required to obtain the observed diffraction pattern. The oxygen configurations found are unlikely to give rise to hole doping of the ${mathrm{CuO}}_{2}$ planes, explaining why a higher oxygen doping is necessary in ${mathrm{NdBa}}_{2}{mathrm{Cu}}_{3}{mathrm{O}}_{6+x}$ than in ${mathrm{YBa}}_{2}{mathrm{Cu}}_{3}{mathrm{O}}_{6+x}$ to make the compound superconducting." @default.
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• W2048568926 date "2000-04-01" @default.
• W2048568926 modified "2023-09-27" @default.
• W2048568926 title "Oxygen-ordering superstructures inNdBa2Cu3O6.5single crystals investigated by hard-x-ray diffraction" @default.
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• W2048568926 doi "https://doi.org/10.1103/physrevb.61.r9253" @default.
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