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- W2048572964 abstract "Abstract Reaction of the (η4-butadiene)Zr(C5H4R)2 complexes, 1a (R = t-butyl) or 1b (R = 1,1-dimethylpentyl), with elemental tellurium at 70°C in toluene for 30 h leads to liberation of the butadiene ligand and formation of the compounds [(η-C5H4R)2ZrTe]2 (2,ab). 2a crystallizes in the space group P21/c with cell parameters a 9.517(4), b 12.273(5), c 15.664(7) A, β 96.72(3)°. In the crystal state 2a exhibits a square planar Zr2Te2 framework (d(ZrTe) 2.855(1) A; TeZrTe* 89.14(1), ZrTeZr* 90.86(1)°)." @default.
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- W2048572964 date "1986-10-01" @default.
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- W2048572964 title "Metallocen-chalcogen-verbindungen: Eine einfache synthese von [(η-C5H4R)2ZrTe]2 komplexen mit einem planaren metallacyclischen vierringgerüst" @default.
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- W2048572964 doi "https://doi.org/10.1016/0022-328x(86)80373-4" @default.
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