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• W2048576554 abstract "A new asymmetric route for the synthesis of trans-2-aryl- and -heteroaryl-substituted cyclopropylboronates has been developed. (Z)-3-arylallylic phosphates were converted to the optically active products with high yield and diastereo- and enantioselectivity through a copper(I)-catalyzed reaction with a diboron derivative. Under mild reaction conditions, the reaction affords the arylcyclopropane products with a functional group and a heteroaromatic group in a highly enantioselective manner. When (E)-allylic phosphates were used as substrates, a ligand-controlled product switch between the trans and cis configurations was observed." @default.
• W2048576554 created "2016-06-24" @default.
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• W2048576554 date "2010-08-04" @default.
• W2048576554 modified "2023-10-05" @default.
• W2048576554 title "Enantioselective Synthesis of <i>trans</i>-Aryl- and -Heteroaryl-Substituted Cyclopropylboronates by Copper(I)-Catalyzed Reactions of Allylic Phosphates with a Diboron Derivative" @default.
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• W2048576554 doi "https://doi.org/10.1021/ja103783p" @default.
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