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• W2048599437 abstract "Equilibrium temperatures for solid–liquid transitions of mixtures formed by sulfolane and ethanenitrile, propanenitrile, butanenitrile, or pentanenitrile were measured by a dynamic method. The solid–liquid equilibria phase diagrams show positive deviations from Raoult's law, except for the system with ethanenitrile, which is nearly ideal. The sulfolane–nitrile and sulfolane–1-alkyne interactions have been characterized in terms of the DISQUAC group contribution model. DISQUAC properly represents a complete set of thermodynamic properties: solid–liquid equilibria, molar excess enthalpies, and natural logarithms of activity coefficients. DISQUAC predictions are valid over a wide temperature range.Key words: solid–liquid equilibria, thermodynamics, mixtures, interactions." @default.
• W2048599437 created "2016-06-24" @default.
• W2048599437 creator A5017577532 @default.
• W2048599437 creator A5067619915 @default.
• W2048599437 date "2002-05-01" @default.
• W2048599437 modified "2023-10-16" @default.
• W2048599437 title "Thermodynamics of mixtures containing a very strongly polar compound. Part II. Solid-liquid equilibria for sulfolane + nitrile systems and characterization of the sulfolane-nitrile and sulfolane-1-alkyne interactions in terms of DISQUAC" @default.
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• W2048599437 doi "https://doi.org/10.1139/v02-066" @default.
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