FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2048653642> ?p ?o ?g. }

• W2048653642 endingPage "1390" @default.
• W2048653642 startingPage "1383" @default.
• W2048653642 abstract "Metal-ion-templated cyclocondensations of two acyclic diamines containing nitrogen and sulfur heteroatoms with pyridine-2,6-dicarbaldehyde in the presence of the ions PbII, HgII, CdII and AgI afforded 1 : 1 complexes of the appropriate metal ion with the corresponding 18-membered, potentially sexidentate (N4S2), diimine macrocycle L1 or L2. The soluble lead, mercury and cadmium complexes show strong metal–imine interactions in the NMR spectra: they are rare examples of co-ordination compounds of these ions that exhibit satellites due to proton and carbon-13 coupling to the naturally abundant metal nuclei with spin I=½. The crystal structures of the complexes [PbL1(MeOH)(H2O)][ClO4]21a and [HgL1(SCN)2]·MeOH 2 have been determined. In both complexes the macrocycle adopts a stepped conformation with respect to the two pyridyl units; this conformation facilitates endo-dentate configurations for the sulfur donors which interact through long bonds to the metal which, in turn, is located towards the trimethine part of the macrocycle. The combination of the asymmetrical location of the metal ion within the macrocyclic cavity and the long bonds to the sulfurs leaves the second pyridine nitrogen remote and unco-ordinated. The metal geometry in 1a is best described as a very distorted nido-hexagonal bipyramid in which the macrocycle donors occupy five of the six ‘quatorial’ sites and solvent molecules define severely bent ‘axial’ positions, implicating a stereochemically active role for the 6s2 lone-pair electrons on PbII. The structure of 2 is similar to that of 1a but the axial positions are linear and occupied by thiocyanate ions; in contrast to 1a, the mercury atom is displaced well out of the plane of the trimethine co-ordinating fragment. Both are rare examples of structural characterisations of the interaction of mixed nitrogen–sulfur-donor macrocycles with these toxic heavy-metal ions." @default.
• W2048653642 created "2016-06-24" @default.
• W2048653642 creator A5010813615 @default.
• W2048653642 creator A5018986886 @default.
• W2048653642 creator A5055319982 @default.
• W2048653642 creator A5085079173 @default.
• W2048653642 creator A5086789324 @default.
• W2048653642 date "1994-01-01" @default.
• W2048653642 modified "2023-09-26" @default.
• W2048653642 title "Interaction of environmentally important metal ions with nitrogen–sulfur-donor macrocycles. The crystal structures of seven-co-ordinate lead(<scp>II</scp>) and mercury(<scp>II</scp>) complexes of an 18-membered N₄S₂macrocycle" @default.
• W2048653642 cites W1964441349 @default.
• W2048653642 cites W1983420176 @default.
• W2048653642 cites W2000027171 @default.
• W2048653642 cites W2000084992 @default.
• W2048653642 cites W2005603297 @default.
• W2048653642 cites W2006512374 @default.
• W2048653642 cites W2009837825 @default.
• W2048653642 cites W2015085543 @default.
• W2048653642 cites W2016122226 @default.
• W2048653642 cites W2017345869 @default.
• W2048653642 cites W2027629018 @default.
• W2048653642 cites W2038783313 @default.
• W2048653642 cites W2039815243 @default.
• W2048653642 cites W2041605955 @default.
• W2048653642 cites W2049533192 @default.
• W2048653642 cites W2049791597 @default.
• W2048653642 cites W2054267317 @default.
• W2048653642 cites W2057936845 @default.
• W2048653642 cites W2060074617 @default.
• W2048653642 cites W2064078667 @default.
• W2048653642 cites W2068274661 @default.
• W2048653642 cites W2072692422 @default.
• W2048653642 cites W2074941644 @default.
• W2048653642 cites W2075819011 @default.
• W2048653642 cites W2076137140 @default.
• W2048653642 cites W2083846377 @default.
• W2048653642 cites W2101748147 @default.
• W2048653642 cites W2105767327 @default.
• W2048653642 cites W2144501009 @default.
• W2048653642 cites W2158322213 @default.
• W2048653642 cites W2167590372 @default.
• W2048653642 cites W4292934244 @default.
• W2048653642 doi "https://doi.org/10.1039/dt9940001383" @default.
• W2048653642 hasPublicationYear "1994" @default.
• W2048653642 type Work @default.
• W2048653642 sameAs 2048653642 @default.
• W2048653642 citedByCount "34" @default.
• W2048653642 countsByYear W20486536422014 @default.
• W2048653642 countsByYear W20486536422015 @default.
• W2048653642 crossrefType "journal-article" @default.
• W2048653642 hasAuthorship W2048653642A5010813615 @default.
• W2048653642 hasAuthorship W2048653642A5018986886 @default.
• W2048653642 hasAuthorship W2048653642A5055319982 @default.
• W2048653642 hasAuthorship W2048653642A5085079173 @default.
• W2048653642 hasAuthorship W2048653642A5086789324 @default.
• W2048653642 hasConcept C115624301 @default.
• W2048653642 hasConcept C161790260 @default.
• W2048653642 hasConcept C178790620 @default.
• W2048653642 hasConcept C185592680 @default.
• W2048653642 hasConcept C199164860 @default.
• W2048653642 hasConcept C20950531 @default.
• W2048653642 hasConcept C2776303508 @default.
• W2048653642 hasConcept C2776573223 @default.
• W2048653642 hasConcept C2779485729 @default.
• W2048653642 hasConcept C2780378348 @default.
• W2048653642 hasConcept C32909587 @default.
• W2048653642 hasConcept C46000676 @default.
• W2048653642 hasConcept C518881349 @default.
• W2048653642 hasConcept C544153396 @default.
• W2048653642 hasConcept C71240020 @default.
• W2048653642 hasConcept C8010536 @default.
• W2048653642 hasConceptScore W2048653642C115624301 @default.
• W2048653642 hasConceptScore W2048653642C161790260 @default.
• W2048653642 hasConceptScore W2048653642C178790620 @default.
• W2048653642 hasConceptScore W2048653642C185592680 @default.
• W2048653642 hasConceptScore W2048653642C199164860 @default.
• W2048653642 hasConceptScore W2048653642C20950531 @default.
• W2048653642 hasConceptScore W2048653642C2776303508 @default.
• W2048653642 hasConceptScore W2048653642C2776573223 @default.
• W2048653642 hasConceptScore W2048653642C2779485729 @default.
• W2048653642 hasConceptScore W2048653642C2780378348 @default.
• W2048653642 hasConceptScore W2048653642C32909587 @default.
• W2048653642 hasConceptScore W2048653642C46000676 @default.
• W2048653642 hasConceptScore W2048653642C518881349 @default.
• W2048653642 hasConceptScore W2048653642C544153396 @default.
• W2048653642 hasConceptScore W2048653642C71240020 @default.
• W2048653642 hasConceptScore W2048653642C8010536 @default.
• W2048653642 hasIssue "9" @default.
• W2048653642 hasLocation W20486536421 @default.
• W2048653642 hasOpenAccess W2048653642 @default.
• W2048653642 hasPrimaryLocation W20486536421 @default.
• W2048653642 hasRelatedWork W1553419333 @default.
• W2048653642 hasRelatedWork W1814339382 @default.
• W2048653642 hasRelatedWork W2012345717 @default.
• W2048653642 hasRelatedWork W2019388717 @default.
• W2048653642 hasRelatedWork W2070629195 @default.
• W2048653642 hasRelatedWork W2133078045 @default.
• W2048653642 hasRelatedWork W2891450946 @default.

• next