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- W2048654941 abstract "Although there are two F1u components in 3ν3 of UF6 and transitions are allowed from the vibrational ground state to both, only a single band has been observed in the ir spectrum. These two states may be identified in a Cartesian representation of the normal coordinates as 3ν3x and 2ν3x+ν3y; on the basis of calculated intensities, the observed transition has been assigned to 3ν3x. The calculation of the dipole strengths required us to derive the octahedral splitting parameters G33 and T33 and these have been used to calculate the anharmonic splittings in the ν3 vibrational manifolds of 238UF6 and 235UF6." @default.
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- W2048654941 date "1978-03-15" @default.
- W2048654941 modified "2023-10-17" @default.
- W2048654941 title "3-quantum transition probabilities in the ν3 manifold of UF6 and the assignment of 3ν3 in the observed infrared spectrum" @default.
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- W2048654941 doi "https://doi.org/10.1063/1.436064" @default.
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