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• W2048705087 abstract "The common facets of anatase crystals are the (001) and (101) planes. However, the phase transformation from lepidocrocite-type titanate into anatase by hydrothermal processing yields an anatase microstructure with high concentration of exposed (010) planes. The phase transformation of a lepidocrocite-type protonated layered titanate (HTO) into anatase was studied using XRD, TEM, FTIR, and measurement of pH and zeta potential. It was found that HTO is proton-deficient. The phase transformation process begins after uptake of a sufficient number of protons into the lepidocrocite-type structure. With the uptake of protons new hydroxyl groups form on the internal surfaces of the layered titanate and result in a bilayer state of HTO. The phase transformation reaction is a topotactic dehydration reaction in which anatase forms and water is expelled by syneresis." @default.
• W2048705087 created "2016-06-24" @default.
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• W2048705087 date "2014-04-03" @default.
• W2048705087 modified "2023-10-01" @default.
• W2048705087 title "The swelling transition of lepidocrocite-type protonated layered titanates into anatase under hydrothermal treatment" @default.
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• W2048705087 doi "https://doi.org/10.1038/srep04584" @default.
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