Matches in SemOpenAlex for { <https://semopenalex.org/work/W2048708843> ?p ?o ?g. }
Showing items 1 to 91 of
91
with 100 items per page.
- W2048708843 endingPage "8527" @default.
- W2048708843 startingPage "8521" @default.
- W2048708843 abstract "Laser-induced dispersed fluorescence spectra of benzoic acid dimer in the cold environment of supersonic jet expansion have been reinvestigated with improved spectral resolution of measurements. The spectra are analyzed with the aid of the normal mode vibrations of the dimer calculated by the ab initio quantum chemistry method at the DFT/B3LYP/6-311+G** level of theory. The analysis reveals that the low-frequency intermolecular hydrogen bond modes are mixed extensively with the carboxyl as well as aromatic ring vibrations upon electronic excitation. The mode mixing is manifested as the complete loss of mirror symmetry relation between the fluorescence excitation and dispersed fluorescence spectra of the S1 origin, and appearance of large number of cross-sequence transitions when the DF spectra are measured by exciting the low-energy vibrations near the S1 origin. The cross-sequence bands are found in all the cases to be the combinations of two nontotally symmetric fundamentals consisting of one of the intermolecular hydrogen bond modes and the other from the aromatic ring and carboxyl group vibrations. The implications of this mode mixing on the excited state dynamics of the dimer are discussed." @default.
- W2048708843 created "2016-06-24" @default.
- W2048708843 creator A5043498807 @default.
- W2048708843 creator A5078684292 @default.
- W2048708843 date "2004-04-20" @default.
- W2048708843 modified "2023-09-30" @default.
- W2048708843 title "Hydrogen bond-induced vibronic mode mixing in benzoic acid dimer: A laser-induced fluorescence study" @default.
- W2048708843 cites W1974711869 @default.
- W2048708843 cites W1974831736 @default.
- W2048708843 cites W1991204396 @default.
- W2048708843 cites W1998521811 @default.
- W2048708843 cites W1999769747 @default.
- W2048708843 cites W2003581343 @default.
- W2048708843 cites W2010092390 @default.
- W2048708843 cites W2013064897 @default.
- W2048708843 cites W2020737653 @default.
- W2048708843 cites W2022811211 @default.
- W2048708843 cites W2037821387 @default.
- W2048708843 cites W2038714953 @default.
- W2048708843 cites W2051658312 @default.
- W2048708843 cites W2056768042 @default.
- W2048708843 cites W2064637161 @default.
- W2048708843 cites W2071815120 @default.
- W2048708843 cites W2093114346 @default.
- W2048708843 cites W2168367498 @default.
- W2048708843 cites W2614884730 @default.
- W2048708843 cites W2949899741 @default.
- W2048708843 doi "https://doi.org/10.1063/1.1695312" @default.
- W2048708843 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15267778" @default.
- W2048708843 hasPublicationYear "2004" @default.
- W2048708843 type Work @default.
- W2048708843 sameAs 2048708843 @default.
- W2048708843 citedByCount "18" @default.
- W2048708843 countsByYear W20487088432012 @default.
- W2048708843 countsByYear W20487088432013 @default.
- W2048708843 countsByYear W20487088432019 @default.
- W2048708843 crossrefType "journal-article" @default.
- W2048708843 hasAuthorship W2048708843A5043498807 @default.
- W2048708843 hasAuthorship W2048708843A5078684292 @default.
- W2048708843 hasConcept C112887158 @default.
- W2048708843 hasConcept C120665830 @default.
- W2048708843 hasConcept C121332964 @default.
- W2048708843 hasConcept C1342733 @default.
- W2048708843 hasConcept C166950319 @default.
- W2048708843 hasConcept C178790620 @default.
- W2048708843 hasConcept C181500209 @default.
- W2048708843 hasConcept C184779094 @default.
- W2048708843 hasConcept C185592680 @default.
- W2048708843 hasConcept C2779546866 @default.
- W2048708843 hasConcept C2781442258 @default.
- W2048708843 hasConcept C32909587 @default.
- W2048708843 hasConcept C41999313 @default.
- W2048708843 hasConcept C75473681 @default.
- W2048708843 hasConcept C91881484 @default.
- W2048708843 hasConceptScore W2048708843C112887158 @default.
- W2048708843 hasConceptScore W2048708843C120665830 @default.
- W2048708843 hasConceptScore W2048708843C121332964 @default.
- W2048708843 hasConceptScore W2048708843C1342733 @default.
- W2048708843 hasConceptScore W2048708843C166950319 @default.
- W2048708843 hasConceptScore W2048708843C178790620 @default.
- W2048708843 hasConceptScore W2048708843C181500209 @default.
- W2048708843 hasConceptScore W2048708843C184779094 @default.
- W2048708843 hasConceptScore W2048708843C185592680 @default.
- W2048708843 hasConceptScore W2048708843C2779546866 @default.
- W2048708843 hasConceptScore W2048708843C2781442258 @default.
- W2048708843 hasConceptScore W2048708843C32909587 @default.
- W2048708843 hasConceptScore W2048708843C41999313 @default.
- W2048708843 hasConceptScore W2048708843C75473681 @default.
- W2048708843 hasConceptScore W2048708843C91881484 @default.
- W2048708843 hasIssue "18" @default.
- W2048708843 hasLocation W20487088431 @default.
- W2048708843 hasLocation W20487088432 @default.
- W2048708843 hasOpenAccess W2048708843 @default.
- W2048708843 hasPrimaryLocation W20487088431 @default.
- W2048708843 hasRelatedWork W1951590065 @default.
- W2048708843 hasRelatedWork W1974302504 @default.
- W2048708843 hasRelatedWork W1995629181 @default.
- W2048708843 hasRelatedWork W2043651856 @default.
- W2048708843 hasRelatedWork W2053874357 @default.
- W2048708843 hasRelatedWork W2083795371 @default.
- W2048708843 hasRelatedWork W2092351220 @default.
- W2048708843 hasRelatedWork W2092662459 @default.
- W2048708843 hasRelatedWork W2165994172 @default.
- W2048708843 hasRelatedWork W3026266487 @default.
- W2048708843 hasVolume "120" @default.
- W2048708843 isParatext "false" @default.
- W2048708843 isRetracted "false" @default.
- W2048708843 magId "2048708843" @default.
- W2048708843 workType "article" @default.