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- W2048760136 abstract "A series of 4-nitro-1-cyclobuten-l-amines 3 was isolated from the thermal (2 + 2) cycloaddition of nitro(cyclo)alkenes 1 and ynamines 2. Heating of 3a-d yielded products corresponding with disrotatory ring opening viz. the 1,3-dienes 6a-d. Heating of 3e,f at 60°C gave the dienes 7a,b, as the result of a conrotatory ring opening reaction, together with the trans-2-nitrocyclobutenes 8a,b, as the result of a hydrogen shift in the cyclobutene ring. Upon prolonged heating at 80°C 8b was converted into the diene 7b. Treatment of 3e with acid yielded the 2-nitrocyclobutenes 9a and 9b. The structures of 3a, 3f, 6a and 7b were elucidated by X-ray analysis. The formation of 6a-d is attributed to E/Z isomerization of the product, initially formed by a conrotatory ring opening." @default.
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- W2048760136 date "1988-01-01" @default.
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- W2048760136 title "The (apparently disrotatory) thermal ring opening of 4-nitro-1-cyclobuten-1 -amines" @default.
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- W2048760136 doi "https://doi.org/10.1002/recl.19881070203" @default.
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