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- W2048778875 abstract "The low-temperature inelastic neutron scattering spectrum measured for the p-tert-butylcalix[4]arene(2:1)p-xylene complex has been interpreted in the framework of a quantum dynamical model assuming a rotational motion of the p-xylene groups correlated to the translational motion of their centre of mass. By comparing the experimental data with calculated energies and intensities, the effective anharmonic and anisotropic molecular potential experienced by the methyl groups has been derived. The wavefunctions deduced from the spectroscopy results are used to calculate the proton density distribution in the plane of the motion." @default.
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- W2048778875 date "1998-03-16" @default.
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- W2048778875 title "Coherent internal and centre of mass quantum rotation of methyl groups in thep-tert-butyl-calix[4]arene(2:1)p-xylene supramolecular complex" @default.
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- W2048778875 doi "https://doi.org/10.1088/0953-8984/10/10/006" @default.
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