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- W2048798423 abstract "Boron trichloride and dimethyl sulfide form a 1:1 complex. It exchanges with excess boron trichloride by a displacement mechanism with an activation energy of 5.0 ± 0.5 kcal/mol and with excess dimethyl sulfide by a dissociation mechanism which has an activation energy of 20 ± 1 kcal/mol. The 1:1 complex of AlCl 3 and dimethyl sulfide exchanges very rapidly with excess dimethyl sulfide. Equilibria and exchange reactions of AlCl 3 [(CH 3 ) 2 O], AlCl 3 [(CH 3 ) 2 O] 2 , and (CH 3 ) 2 O are described. Rapid exchange is always found in the analogous gallium systems. BCl 3 reacts with chloride ion to give BCl 4 − and B 2 Cl 7 − , which exchange rapidly with excess BCl 3 . AlCl 3 reacts with Cl − and BCl 4 − to give AlCl 4 − which does not exchange with AlCl 3 ." @default.
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- W2048798423 date "1981-10-15" @default.
- W2048798423 modified "2023-10-18" @default.
- W2048798423 title "Complexing and exchange of boron, aluminum, and gallium chlorides with some Lewis bases" @default.
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- W2048798423 doi "https://doi.org/10.1139/v81-436" @default.
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