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- W2048813202 abstract "Proton transfer from the triplet excited state of brominated naphthol to a difluoroboryl bridged Co(I)-diglyoxime complex, forming Co(III)H, was monitored via transient absorption. The second-order rate constant for Co(III)H formation is in the range (3.5-4.7) × 10(9) M(-1) s(-1), with proton transfer coupled to excited-state deactivation of the photoacid. Co(III)H is subsequently reduced by excess Co(I)-diglyoxime in solution to produce Co(II)H (k(red) = 9.2 × 10(6) M(-1) s(-1)), which is then protonated to yield Co(II)-diglyoxime and H(2)." @default.
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- W2048813202 date "2010-11-10" @default.
- W2048813202 modified "2023-09-30" @default.
- W2048813202 title "Mechanism of H<sub>2</sub> Evolution from a Photogenerated Hydridocobaloxime" @default.
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- W2048813202 doi "https://doi.org/10.1021/ja109351h" @default.
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