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- W2048822182 abstract "Reaction of [Et4N]2[Fe(SPh)4] with CyNC in MeCN yields cis- and trans-Fe(CyNC)4(SPh)2 which have been identified by their IR spectral data and physical properties. The less-soluble trans isomer converts spontaneously into its cis analog in MeCN by a first order process with kobs = 1.5 x 10−4 s−1 at 20°C. Cyclic voltammetry studies show that the trans isomer undergoes clean, pseudoreversible, one-electron oxidation with E12 = −0.28 V, while cis-Fe(CyNC)4(SPh)2 is oxidized in a multistep, irreversible process at more positive potentials. Both forms of Fe(CyNC)4(SPh)2 react with the substitution-labile carbonylmolybdenum(0) species, (norbornadiene)Mo(CO)4, to generate the new binuclear mixed-metal complex (CyNC)4Fe(SPh)2Mo(CO)4. Cyclic voltammetry of the hetereometallic species shows two pseudoreversible oxidative redox events which formally correspond to FeII/FeIII and Mo0/MoI couples." @default.
- W2048822182 created "2016-06-24" @default.
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- W2048822182 date "1988-05-01" @default.
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- W2048822182 title "Synthesis of cis- and trans-Fe(CyNC)4(SPh)2: bis-thiolate precursors of the mixed-metal complex, (CyNC)4Fe(SPh)2Mo(CO)4" @default.
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- W2048822182 doi "https://doi.org/10.1016/0022-328x(88)80243-2" @default.
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