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• W2048828552 abstract "Viscosities of dilute polymer solutions were measured in capillary viscometers for samples varying in their fraction f of charged units from 0.00 to 0.90. The dependence of the logarithm of the relative viscosity on polymer concentration c is in all cases reproduced quantitatively by three characteristic parameters: [η], the intrinsic viscosity; B, a viscometric interaction parameter (related to the Huggins constant); [η], a parameter required only for polyelectrolytes at low concentrations of extra salt. In pure water [η] increases more than 80 times as the fraction f rises from zero to 0.90 and [η] starts from zero and goes up to ≈71mL/g. Upon the addition of NaCl [η] decreases by at least one order of magnitude (depending on the value of f). The observed dependences of log [η] on logcsalt can be modeled quantitatively by Boltzmann sigmoids." @default.
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• W2048828552 date "2012-01-01" @default.
• W2048828552 modified "2023-10-04" @default.
• W2048828552 title "Intrinsic viscosities of polyelectrolytes in the absence and in the presence of extra salt: Consequences of the stepwise conversion of dextran into a polycation" @default.
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• W2048828552 doi "https://doi.org/10.1016/j.carbpol.2011.07.067" @default.
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