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- W2048841683 abstract "The reactions of (1,3-dithiolan-2-yl)trimethylammonium iodide (5), readily obtained by methylation of 2-dimethylamino-1,3-dithiolane (2), with aromatic amines were studied. It was found that 5 served as an electrophilic 1,3-dithiolanylating reagent; the reactions with aniline, N-methylaniline, and benzylamine gave N-dithiolanylated products while those with N,N-dimethylaniline and indole yielded exclusively C-dithiolanylated products via aromatic substitutions. Furthermore, C-dithiolanylated compounds were hydrolyzed to aldehydes using HgO–BF3·OEt2. The present aldehyde synthesis has been compared with an alternative electrophilic formylation method the Vilsmeier reaction." @default.
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- W2048841683 date "1973-11-01" @default.
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- W2048841683 title "(1,3-Dithiolan-2-yl)trimethylammonium Iodide. An Electrophilic Dithiolanylating Reagent" @default.
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- W2048841683 doi "https://doi.org/10.1246/bcsj.46.3510" @default.
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