Matches in SemOpenAlex for { <https://semopenalex.org/work/W2048859546> ?p ?o ?g. }
Showing items 1 to 79 of
79
with 100 items per page.
- W2048859546 endingPage "3526" @default.
- W2048859546 startingPage "3521" @default.
- W2048859546 abstract "Abstract The use of a mono-pivalate mono-acrylate bis-ester of (+)-1S,5S,6S-spiro[4.4]nonane-1,6-diol in an asymmetric Diels-Alder reaction with cyclopentadiene (2 equiv. BCl3, −85°C, CH2Cl2) provided the expected endo bicyclo adduct in >97% de. Iodolactonization of the bicyclo adduct provided the (+)-lactone (5) with a 1S,4S,6S,8R,9S configuration (97% ee). The de's obtained from using various types and amounts of Lewis acids, and both chiral and racemic bis-esters in the Diels-Alder reaction with cyclopentadiene are also reported." @default.
- W2048859546 created "2016-06-24" @default.
- W2048859546 creator A5073816644 @default.
- W2048859546 creator A5091001053 @default.
- W2048859546 date "1996-12-01" @default.
- W2048859546 modified "2023-10-10" @default.
- W2048859546 title "cis,cis-Spiro[4.4]nonane-1,6-diol: A new chiral auxiliary for the asymmetric Diels-Alder reaction" @default.
- W2048859546 cites W1972024949 @default.
- W2048859546 cites W1978941203 @default.
- W2048859546 cites W1988951563 @default.
- W2048859546 cites W1989190481 @default.
- W2048859546 cites W1990836197 @default.
- W2048859546 cites W1996363340 @default.
- W2048859546 cites W1997658110 @default.
- W2048859546 cites W2000201317 @default.
- W2048859546 cites W2014972141 @default.
- W2048859546 cites W2021976919 @default.
- W2048859546 cites W2029330943 @default.
- W2048859546 cites W2042249123 @default.
- W2048859546 cites W2086041166 @default.
- W2048859546 cites W2102110064 @default.
- W2048859546 cites W2949488062 @default.
- W2048859546 cites W2951131805 @default.
- W2048859546 doi "https://doi.org/10.1016/s0957-4166(96)00459-4" @default.
- W2048859546 hasPublicationYear "1996" @default.
- W2048859546 type Work @default.
- W2048859546 sameAs 2048859546 @default.
- W2048859546 citedByCount "22" @default.
- W2048859546 countsByYear W20488595462014 @default.
- W2048859546 countsByYear W20488595462016 @default.
- W2048859546 countsByYear W20488595462018 @default.
- W2048859546 crossrefType "journal-article" @default.
- W2048859546 hasAuthorship W2048859546A5073816644 @default.
- W2048859546 hasAuthorship W2048859546A5091001053 @default.
- W2048859546 hasConcept C146686406 @default.
- W2048859546 hasConcept C161790260 @default.
- W2048859546 hasConcept C178790620 @default.
- W2048859546 hasConcept C185592680 @default.
- W2048859546 hasConcept C2778265757 @default.
- W2048859546 hasConcept C2778499038 @default.
- W2048859546 hasConcept C2779061078 @default.
- W2048859546 hasConcept C2779515768 @default.
- W2048859546 hasConcept C2779940776 @default.
- W2048859546 hasConcept C59822182 @default.
- W2048859546 hasConcept C71240020 @default.
- W2048859546 hasConcept C86803240 @default.
- W2048859546 hasConceptScore W2048859546C146686406 @default.
- W2048859546 hasConceptScore W2048859546C161790260 @default.
- W2048859546 hasConceptScore W2048859546C178790620 @default.
- W2048859546 hasConceptScore W2048859546C185592680 @default.
- W2048859546 hasConceptScore W2048859546C2778265757 @default.
- W2048859546 hasConceptScore W2048859546C2778499038 @default.
- W2048859546 hasConceptScore W2048859546C2779061078 @default.
- W2048859546 hasConceptScore W2048859546C2779515768 @default.
- W2048859546 hasConceptScore W2048859546C2779940776 @default.
- W2048859546 hasConceptScore W2048859546C59822182 @default.
- W2048859546 hasConceptScore W2048859546C71240020 @default.
- W2048859546 hasConceptScore W2048859546C86803240 @default.
- W2048859546 hasIssue "12" @default.
- W2048859546 hasLocation W20488595461 @default.
- W2048859546 hasOpenAccess W2048859546 @default.
- W2048859546 hasPrimaryLocation W20488595461 @default.
- W2048859546 hasRelatedWork W1526798589 @default.
- W2048859546 hasRelatedWork W1965664858 @default.
- W2048859546 hasRelatedWork W2195912495 @default.
- W2048859546 hasRelatedWork W2496363768 @default.
- W2048859546 hasRelatedWork W2795470142 @default.
- W2048859546 hasRelatedWork W2945849620 @default.
- W2048859546 hasRelatedWork W4206855106 @default.
- W2048859546 hasRelatedWork W4246254444 @default.
- W2048859546 hasRelatedWork W597116207 @default.
- W2048859546 hasRelatedWork W2158774620 @default.
- W2048859546 hasVolume "7" @default.
- W2048859546 isParatext "false" @default.
- W2048859546 isRetracted "false" @default.
- W2048859546 magId "2048859546" @default.
- W2048859546 workType "article" @default.