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- W2048869314 abstract "Abstract We present a novel combinatorial multicomponent regio-selective approach towards the synthesis of thieno[3,2-b]pyridines and pyridine pyrans. The methodology is based on the ‘domino’-type reaction. The high regio-selectivity in this reaction is gained by the in situ generation of the mono-potassium salt of 2-cyano-1-mercaptoethenethiolate. We also demonstrate that the use of ethyl 2-cyanoacetate in this reaction as a CH-acid leads to the termination of the domino sequence at the Dieckmann condensation step and yields novel ethyl 3-(4-cyano-3-hydroxy-5-(alkylthio)thiophen-2-yl)-3-oxopropanoate." @default.
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- W2048869314 date "2014-02-27" @default.
- W2048869314 modified "2023-09-27" @default.
- W2048869314 title "ChemInform Abstract: New Regio-Selective Method of Combinatorial Synthesis of Substituted Thiophenes, Thieno[3,2-b]pyridines and Other Heterocycles via Combination of ′Domino′-Type Reactions." @default.
- W2048869314 cites W2951204249 @default.
- W2048869314 doi "https://doi.org/10.1002/chin.201411181" @default.
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