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- W2048870104 abstract "Oxidation of 5α-stigmast-22-en-3- one (1) with m-chloroperbenzoic acid afforded [22R,23R]-epoxide 3 and [22S, 23S]-epoxide 2, in a 5:3 ratio. Reaction of 1 with iodine/silver acetate gave a mixture of iodoacetates 8 and 9, which on treatment with base yielded the single epoxide 2. Those results suggest that electrophiles may preferentially approach the Δ22-bond from the side of the 21-Me group, in accordance with observations with the ergosterol-like side chain." @default.
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- W2048870104 date "1975-01-01" @default.
- W2048870104 modified "2023-10-01" @default.
- W2048870104 title "Stereoselectivity in the electrophilic addition reactions of stigmast-22(23)-ene derivatives" @default.
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- W2048870104 doi "https://doi.org/10.1016/0040-4020(75)80285-7" @default.
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