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- W2048884554 abstract "Ynamines 2 bearing methyl or phenyl groups at their C/C triple bond react with tert-butylcyanoketene 1a to give the cyclobutenones 3 and/or the allene carboxamides 4. 3 and 4 are the products of two different [2 + 2] cycloaddition reactions. β-Silylated, β-germylated and β-stannylated ynamines 5 add the cyanoketenes 1 under (aminoethynyl)metallation to furnish the new enynamines 6. These compounds were characterized by IR and 1 H NMR spectroscopy and partly by mass spectrometry. The stannyl derivatives of 6 hydrolyze very easily to the corresponding acyl ynamines 7 and react with 4-nitrobenzoyl chloride to give the 1-(aminoethynyl)vinyl benzoates 8. The diazo compound 9 is formed by the interaction of tosyl azide on the enynamine 6 c, which is probably first hydrolyzed to 7a. N,N-Diethyl-N-(triphenylsilylethynyl)amine (5e) reacts with two molecules of tert-butylcyanoketene (1a) to give the allene derivative 10, probably via the corresponding enynamine 6 (R 1 = R 2 = Et, MR 3 3 = SiPh 3 , R 4 -tBu)." @default.
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- W2048884554 date "1981-02-01" @default.
- W2048884554 modified "2023-10-09" @default.
- W2048884554 title "(Aminoethinyl)metallierimgen, IX [1] Umsetzungen von Inaminen mit Cyanketenen / (Aminoethynyl)metallations, IX [1] Reactions of Ynamines with Cyanoketenes" @default.
- W2048884554 doi "https://doi.org/10.1515/znb-1981-0218" @default.
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