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• W2048889032 abstract "2,14-Dithiacalix[4]arene 34 was conveniently prepared in 16% yield by acid-catalyzed cyclocondensation of 2,2′-thiobis[4-tert-butylphenol] with formaldehyde. The present method also afforded the first isolation of the analogues with six and eight phenol units, 36 (10%) and 38 (5%), respectively. Solvent extraction showed that 34 had high selectivity toward Cu2+ ion at pH 5.5 by coordination of the bridging sulfur with cooperative donation of the adjacent phenolate oxygens." @default.
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• W2048889032 date "2004-01-01" @default.
• W2048889032 modified "2023-10-16" @default.
• W2048889032 title "Facile synthesis of thiacalix[n]arenes (n=4, 6, and 8) consisting of p-tert-butylphenol and methylene/sulfide alternating linkage and metal-binding property of the n=4 homologue" @default.
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• W2048889032 doi "https://doi.org/10.1016/j.tetlet.2003.10.121" @default.
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