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- W2048891234 abstract "The half-sandwich molybdenum(III) complex CpMoCl2(iPr2-dad) (iPr2-dad=iPr–NCH–CHN–iPr) proved to be an effective metal catalyst for the controlled radical polymerization of methyl acrylate, butyl acrylate, and styrene. In conjunction with an alkyl iodide [R–I: CH3CH(COOEt)I] as an initiator and in the presence or absence of Al(O–i-Pr)3 as a co-catalyst, the molybdenum-based system gave polymers with narrow molecular weight distributions. The in situ addition of styrene to a macroinitiator of poly(methylacrylate) afforded an AB-type block copolymer." @default.
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- W2048891234 date "2003-11-01" @default.
- W2048891234 modified "2023-10-18" @default.
- W2048891234 title "Controlled radical polymerization of alkyl acrylates and styrene using a half-sandwich molybdenum(III) complex containing diazadiene ligands" @default.
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- W2048891234 doi "https://doi.org/10.1016/s0014-3057(03)00152-6" @default.
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