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- W2048917812 abstract "Pulse radiolysis has been used to measure directly the absolute rates of oxidation by ferricyanide ion of various radicals produced by OH attack on organic solutes. These include mono, di- and polyhydroxylic compounds, hydroxy acids, polyethylene oxides of molecular weight 200, 6000 and 20 000 and the amino acid serine. Radicals produced by hydrogen abstraction from α carbon atoms in alcohols are oxidized at, or near, diffusion-controlled rates, whereas the reactions are much slower for radicals formed by OH-attack elsewhere. The technique has been used to measure the percentage OH-attack at the α position for a series of straight and branched-chain alcohols." @default.
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- W2048917812 date "1969-01-01" @default.
- W2048917812 modified "2023-10-14" @default.
- W2048917812 title "Pulse radiolysis studies on the oxidation of organic radicals in aqueous solution" @default.
- W2048917812 doi "https://doi.org/10.1039/tf9696502981" @default.
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