Matches in SemOpenAlex for { <https://semopenalex.org/work/W2048940501> ?p ?o ?g. }
- W2048940501 endingPage "3347" @default.
- W2048940501 startingPage "3338" @default.
- W2048940501 abstract "Functionalized trifluoromethyl-substituted salicylates have been synthesized based on AlCl3-mediated cyclocondensation reactions using 4,4-dimethoxy-1,1,1-trifluorobut-3-en-2-one and 1,3-bis(silyloxy)-1,3-butadienes. Simultaneous in situ ATR-FTIR/UV–vis spectroscopic measurements were carried out for mechanistic studies. Real-time in situ spectroscopic investigations reveal the formation of an aluminum trichloride bidentate-butenone adduct as intermediate. The observed band shifts in the respective UV–vis spectra in consequence of complex formation could be explained by theoretical calculations. Lewis acidic solids (Al2O3 and TiO2) were also successfully utilized. Due to the strong substrate adsorption on the solids detected by UV–vis-DRS and FTIR transmission spectroscopy the obtained yields were rather modest." @default.
- W2048940501 created "2016-06-24" @default.
- W2048940501 creator A5009283407 @default.
- W2048940501 creator A5025899821 @default.
- W2048940501 creator A5034600340 @default.
- W2048940501 creator A5038264157 @default.
- W2048940501 creator A5044587003 @default.
- W2048940501 creator A5049688120 @default.
- W2048940501 creator A5090379255 @default.
- W2048940501 date "2013-04-01" @default.
- W2048940501 modified "2023-09-26" @default.
- W2048940501 title "Identification of reaction intermediates in AlCl3-mediated cyclocondensation reactions by simultaneous in situ ATR-FTIR and UV–vis spectroscopy" @default.
- W2048940501 cites W1970887320 @default.
- W2048940501 cites W1971133855 @default.
- W2048940501 cites W1976630487 @default.
- W2048940501 cites W1977691061 @default.
- W2048940501 cites W1979026092 @default.
- W2048940501 cites W1988753504 @default.
- W2048940501 cites W1993526080 @default.
- W2048940501 cites W1995507794 @default.
- W2048940501 cites W2004396158 @default.
- W2048940501 cites W2009631030 @default.
- W2048940501 cites W2016878424 @default.
- W2048940501 cites W2017290326 @default.
- W2048940501 cites W2018077658 @default.
- W2048940501 cites W2018718557 @default.
- W2048940501 cites W2021419691 @default.
- W2048940501 cites W2027668772 @default.
- W2048940501 cites W2039169670 @default.
- W2048940501 cites W2040944669 @default.
- W2048940501 cites W2072614257 @default.
- W2048940501 cites W2081722500 @default.
- W2048940501 cites W2087455011 @default.
- W2048940501 cites W2093142451 @default.
- W2048940501 cites W2098727759 @default.
- W2048940501 cites W2123067001 @default.
- W2048940501 cites W2126254583 @default.
- W2048940501 cites W2128580657 @default.
- W2048940501 cites W2130178520 @default.
- W2048940501 cites W2131350133 @default.
- W2048940501 cites W2140366211 @default.
- W2048940501 cites W2157486040 @default.
- W2048940501 cites W2159923052 @default.
- W2048940501 cites W2164692011 @default.
- W2048940501 cites W2172087043 @default.
- W2048940501 cites W2334420685 @default.
- W2048940501 cites W2950065118 @default.
- W2048940501 cites W2950594895 @default.
- W2048940501 cites W2950604786 @default.
- W2048940501 cites W2950842435 @default.
- W2048940501 cites W2951836383 @default.
- W2048940501 cites W2952132065 @default.
- W2048940501 cites W2952807097 @default.
- W2048940501 cites W3138771661 @default.
- W2048940501 cites W4246359913 @default.
- W2048940501 cites W4249674037 @default.
- W2048940501 cites W4250578678 @default.
- W2048940501 cites W2018284719 @default.
- W2048940501 cites W2063406266 @default.
- W2048940501 doi "https://doi.org/10.1016/j.tet.2013.01.097" @default.
- W2048940501 hasPublicationYear "2013" @default.
- W2048940501 type Work @default.
- W2048940501 sameAs 2048940501 @default.
- W2048940501 citedByCount "6" @default.
- W2048940501 countsByYear W20489405012014 @default.
- W2048940501 countsByYear W20489405012015 @default.
- W2048940501 countsByYear W20489405012020 @default.
- W2048940501 countsByYear W20489405012022 @default.
- W2048940501 countsByYear W20489405012023 @default.
- W2048940501 crossrefType "journal-article" @default.
- W2048940501 hasAuthorship W2048940501A5009283407 @default.
- W2048940501 hasAuthorship W2048940501A5025899821 @default.
- W2048940501 hasAuthorship W2048940501A5034600340 @default.
- W2048940501 hasAuthorship W2048940501A5038264157 @default.
- W2048940501 hasAuthorship W2048940501A5044587003 @default.
- W2048940501 hasAuthorship W2048940501A5049688120 @default.
- W2048940501 hasAuthorship W2048940501A5090379255 @default.
- W2048940501 hasConcept C108204754 @default.
- W2048940501 hasConcept C121332964 @default.
- W2048940501 hasConcept C127413603 @default.
- W2048940501 hasConcept C153642686 @default.
- W2048940501 hasConcept C160892712 @default.
- W2048940501 hasConcept C161790260 @default.
- W2048940501 hasConcept C163638829 @default.
- W2048940501 hasConcept C178790620 @default.
- W2048940501 hasConcept C185592680 @default.
- W2048940501 hasConcept C2777822432 @default.
- W2048940501 hasConcept C32891209 @default.
- W2048940501 hasConcept C42360764 @default.
- W2048940501 hasConcept C49102809 @default.
- W2048940501 hasConcept C62520636 @default.
- W2048940501 hasConcept C65024703 @default.
- W2048940501 hasConcept C66075629 @default.
- W2048940501 hasConcept C75473681 @default.
- W2048940501 hasConceptScore W2048940501C108204754 @default.
- W2048940501 hasConceptScore W2048940501C121332964 @default.
- W2048940501 hasConceptScore W2048940501C127413603 @default.
- W2048940501 hasConceptScore W2048940501C153642686 @default.