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- W2048953672 abstract "Boron-dipyrromethenes containing dithioacetal substituents at 3,5-positions, 3,5-bis(dithioacetal) BODIPYs 1 and 2, were synthesized by treating their corresponding 3,5-diformyl BODIPYs 3 and 4 with excess methyl thioglycolate under mild acid catalyzed reaction conditions. The spectral and electrochemical studies indicated that 3,5-bis(dithioacetal) BODIPYs are less electron deficient compared to 3,5-diformyl BODIPYs. Furthermore, dithioacetal functional groups are very useful for binding metal ions and our studies clearly showed that these dyes can act as selective chemodosimetric probes for the recognition of Hg(II) ions over various other metal ions. The sensing phenomenon employs unique and irreversible Hg(II) promoted deprotection of the dithioacetal groups to aldehyde groups which is clearly demonstrated by absorption, fluorescence, HR-MS and NMR studies. Competitive binding experiments demonstrate that BODIPY 1 can specifically detect Hg(II) ions even in the presence of various other metal ions." @default.
- W2048953672 created "2016-06-24" @default.
- W2048953672 creator A5002660612 @default.
- W2048953672 creator A5066599736 @default.
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- W2048953672 date "2014-06-09" @default.
- W2048953672 modified "2023-09-25" @default.
- W2048953672 title "3,5-Bis(dithioacetal) meso-aryl BODIPYs: selective chemodosimeters for Hg(<scp>ii</scp>) ions" @default.
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- W2048953672 doi "https://doi.org/10.1039/c4nj00593g" @default.
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