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- W2048956712 abstract "Bis(arene)molybdenum (arene = benzene, toluene, or mesitylene) react with allyl chloride giving [(arene)Mo(π-C3H5)Cl]2 dimers. With some tertiary phosphines these give (arene)Mo(π-C3H5)(R3P)Cl which, depending on the nature of the phosphine, react with sodium borohydride and an excess of phosphine forming (arene)Mo(R3P)3 or (arene) Mo(R3P)2H2. The hydrogen ligands may be reversibly displaced by molecular nitrogen giving dinitrogee derivatives (arene)Mo(R3P)2N2 or [(benzene) Mo(Ph3P)2]2N2. Dinitrogen may be displaced by carbon monoxidforming (arene)Mo(R3P)2CO derivatives. The compound [(toluene)Mo(Ph3P)2–N2–(dmpe)Fe(π-C5H5)]+BF4n is also described." @default.
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- W2048956712 date "1973-01-01" @default.
- W2048956712 modified "2023-10-17" @default.
- W2048956712 title "Arene molybdenum chemistry: some π-allyl, dihydride, dinitrogen, and carbonyl derivatives" @default.
- W2048956712 doi "https://doi.org/10.1039/dt9730000301" @default.
- W2048956712 hasPublicationYear "1973" @default.
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