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- W2048984910 startingPage "1077" @default.
- W2048984910 abstract "The counterion binding properties of alginate (Alg) sol and gel were studied by using the membrane potential method, in which membranes were constructed of an Alg layer sandwiched between supporting films. The concentrations of Alg WAlg ranged from 0.0025 to 0.0063 g cm−3, and the membrane potentials were measured in NaCl, MgCl2, and CaCl2 solutions. The effective charge densities of Alg (θ*2) were obtained by curve fittings with the theoretical values of the multimembrane potentials. The ratios of θ*2 to the concentration of uronate units θ0 were found not to depend on WAlg; their mean values were 0.45, 0.28, and 0.12 for Na-, Mg-, and CaAlg. The results of Na- and MgAlg in the sol state were bigger than Manning’s theoretical values. The much smaller values of CaAlg in the gel state than MgAlg in the sol state showed that the Ca ion binding was enhanced by the gellation not only in the junction, but also in the networks." @default.
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- W2048984910 date "1988-04-01" @default.
- W2048984910 modified "2023-10-14" @default.
- W2048984910 title "The Effects of the Sol–Gel Transition of Alginates on Effective Charge Densities" @default.
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- W2048984910 doi "https://doi.org/10.1246/bcsj.61.1077" @default.
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