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• W2048984941 endingPage "2450" @default.
• W2048984941 startingPage "2442" @default.
• W2048984941 abstract "To study the conformations and coordination chemistry of cyclohexane-1,2,4,5-tetracarboxylic acid (H4L), we have obtained four new coordination polymers, [Mn2(μ4-LI)(H2O)6] (1), [Mn2(μ8-LI)(H2O)2] (2), [Mn2(μ7-LII)(H2O)3] (3), and [Ag4(LI)(4,4′-bpy)3]·10H2O (4), from the reactions of Mn(II) or Ag(I) salts with cyclohexane-1e,2a,4a,5e-tetracarboxylic acid (2e+2a, H4LI). A new conformation, cyclohexane-1e,2a,4e,5e-tetracarboxylate (3e+1a, LII), was derived from conformational conversions of LI and trapped in 3 upon coordination by controlling the hydrothermal reaction conditions. The stabilization and separation of different conformations of the flexible organic ligands in coordination structures may help us understand and utilize various interesting conformational transformations. Magnetic studies show that antiferromagnetic interaction occurs in both 1 and 2." @default.
• W2048984941 created "2016-06-24" @default.
• W2048984941 creator A5024424441 @default.
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• W2048984941 creator A5089919376 @default.
• W2048984941 date "2009-03-26" @default.
• W2048984941 modified "2023-10-10" @default.
• W2048984941 title "Coordination Chemistry of Cyclohexane-1,2,4,5-tetracarboxylate (H₄<b>L</b>). Synthesis, Structure, and Magnetic Properties of Metal-Organic Frameworks with Conformation-Flexible H₄L Ligand" @default.
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• W2048984941 doi "https://doi.org/10.1021/cg801348n" @default.
• W2048984941 hasPublicationYear "2009" @default.
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