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- W2049005510 abstract "High surface area α-Al2O3 of 66.2 m2/g was prepared by the thermal decomposition of synthetic diaspore (β-Al2O3·H2O) at 530°C. However, it did not show any catalytic activity for isomerization of 1-butene. On the other hand, γ-Al2O3 obtained from boehmite showed a conversion rate of ca. 70% despite its lower specific surface area of 55 m2/g compared with that of α-Al2O3. This result indicates that the difference in the catalytic activity between α- and γ-Al2O3 is attributable not to the specific surface area, but to the coordination number of the Al ions. Thus, it was experimentally verified for the first time that the octahedral surface Al sites in alumina are inactive for isomerization of 1-butene." @default.
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- W2049005510 date "1993-11-01" @default.
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- W2049005510 title "Preparation of high surface area α-Al2O3 and its surface properties" @default.
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- W2049005510 doi "https://doi.org/10.1016/0926-860x(93)80244-k" @default.
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