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- W2049016502 abstract "Abstract The enhanced catalytic properties toward ethanol electrooxidation on Pt/AlPO 4 nanocomposite thin-film electrodes were investigated. The Pt/AlPO 4 nanocomposites with various Al/Pt ratios (0.27, 0.57, and 0.96) were fabricated by a co-sputtering method. All of the Pt/AlPO 4 nanocomposites showed a negative shift in the onset potential and a higher current density than those of pure Pt electrode for the electrooxidation of ethanol. Among the various Pt/AlPO 4 nanocomposite thin-film electrodes, the electrode with an atomic ratio of Al to Pt of 0.57 showed the highest electrocatalytic activity for ethanol electrooxidation. The activation enthalpy for the optimum Pt/AlPO 4 nanocomposite was approximately 0.05 eV lower than that of pure Pt. It is believed that the enhancement in catalytic activity is due to the electron-rich Pt resulting from the Fermi-energy difference between Pt and AlPO 4 ." @default.
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- W2049016502 date "2012-07-01" @default.
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- W2049016502 title "Pt/AlPO4 nanocomposite thin-film electrodes for ethanol electrooxidation" @default.
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- W2049016502 doi "https://doi.org/10.1016/j.matchemphys.2012.04.051" @default.
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