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• W2049034329 abstract "A model is set up for the description of the chemisorption of a CO molecule on specifically Ni, Pd and Pt surfaces. This is based on the molecular 2 pi * and 5 sigma levels lying within the metal bands, the former above the Fermi level and the latter well below. Broadening of the former into a virtual bound state which can overlap the Fermi level then leads to a situation in which it is demonstrated that one can obtain strong indirect interactions between CO molecules. The amplitude and the phase of the long-range oscillatory form B cos(2KFr+Q)/r5 for separation r between the CO molecules are thereby estimated. The results of this model are then compared with an analysis made of thermal desorption as a function of coverage for CO on Pt. Immediately the strong scattering situation predicted by the above model is revealed, with a phase shift of between pi /4 and pi /2 and a large amplitude B." @default.
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• W2049034329 date "1987-08-10" @default.
• W2049034329 modified "2023-10-18" @default.
• W2049034329 title "Indirect interactions between CO molecules on transition-metal surfaces and the interpretation of thermal desorption experiments" @default.
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• W2049034329 doi "https://doi.org/10.1088/0022-3719/20/22/010" @default.
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