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- W2049061370 abstract "Solutions of I2 + X− (X = Cl, Br, I. NCS) in both water and acetonitrile have been studied by electrospray mass spectrometry in order to identify the anions present. For I2/I−, there is no evidence of the I5− anion proposed earlier to explain deviations from ideality in the formation of I3− in aqueous solution; rather, the equilibrium I3− + I− ⇌ I42− is shown to be compatible with the mass spectrometric results, and with the earlier literature. With Cl−, Br− and NCS−, both classes of solution contain members of the series X3− ⇌ X2I− ⇌ XI2− ⇌ I3−; this is ascribed to rapid redistribution processes rather than to the redox and/or photochemical reactions suggested by earlier workers. There is little qualitative difference between aqueous and acetonitrile solutions, except that aqueous I2/Cl− systems contain the ICl4− anion, whose decomposition in the gas phase produces the previously unknown ICl3˙− radical anion. No I2X− adducts were identified when X = OH−, NCO−, N3− or NO2−." @default.
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- W2049061370 date "2002-12-09" @default.
- W2049061370 modified "2023-10-14" @default.
- W2049061370 title "Studies of polyhalide ions in aqueous and non-aqueous solution by electrospray mass spectrometry" @default.
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- W2049061370 doi "https://doi.org/10.1039/b208035b" @default.
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