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• W2049064052 abstract "The abatement of defects in zeolite membranes is essential for achieving high selectivity. In the present work, a simple and effective method for blocking defects in ultra-thin (ca. 0.5 μm) MFI zeolite membranes has been developed. The method is based on deposition of an ultra-thin (~15 nm) layer of amorphous silica on the top surface of the membrane. Permporometry data indicated that the amount of defects, especially defects larger than 4 nm, in the membranes was significantly reduced after the modification. In mixture separation experiments, the CO2/H2 separation factor increased dramatically after blocking the defects in a defective membrane that was selected for the experiments. For instance, at 263 K and 9 bar feed pressure, the CO2/H2 separation factor increased from 8.5 to 36 after modification of the membrane, whereas the CO2 flux only decreased by ca. 40%." @default.
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• W2049064052 date "2015-09-01" @default.
• W2049064052 modified "2023-09-25" @default.
• W2049064052 title "A simple method for blocking defects in zeolite membranes" @default.
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• W2049064052 doi "https://doi.org/10.1016/j.memsci.2015.04.038" @default.
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