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- W2049069364 abstract "We have synthesized a novel 9,9‘-spirobifluorene-cored donor−acceptor (D−A) bichromophore system in which the electron-donating (D) moieties are triphenylamine (TPA) and carbazole (CBZ) groups and the electron-withdrawing (A) moieties are 1,3,4-oxadiazole (OXD) groups. The electron-deficient OXD groups efficiently blocked the radical cations delocalization between the two terminal TPA groups, rendering the electropolymerization of the TPA groups feasible. The resulting polymer could be cross-linked further at higher oxidation potentials through electrodimerization occurring at the C3 and C6 positions of the CBZ group. The polymer film obtained exhibited reversible electrochemical oxidation, accompanied by strong color changes with high coloration efficiency and contrast ratio, which could be switched through potential modulation." @default.
- W2049069364 created "2016-06-24" @default.
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- W2049069364 date "2007-05-25" @default.
- W2049069364 modified "2023-10-03" @default.
- W2049069364 title "A Novel Electrochromic Polymer Synthesized through Electropolymerization of a New Donor−Acceptor Bipolar System" @default.
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- W2049069364 doi "https://doi.org/10.1021/ma070055m" @default.
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