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- W2049086857 abstract "Abstract In the work reported here we describe an improved procedure for the use of dimethyl-dioxirane, 1, to prepare arene dioxides as well as the isolation and X-ray structure determination of the stereoisomeric dioxides from pyrene, 2, and dibenz[a, h]anthracene, 3. In the case of 2 the dioxides are formed in a 75:25 ratio (cis/trans) and for 3 the dioxide ratio is 45:55 (cis/trans). The X-ray crystallographic structures of both cis dioxides reveal that the oxide groups confer a curvature to the molecular structures." @default.
- W2049086857 created "2016-06-24" @default.
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- W2049086857 date "1999-11-01" @default.
- W2049086857 modified "2023-10-14" @default.
- W2049086857 title "Improved Synthesis and X-Ray Crystallographic Structure Determination of the Stereoisomeric K-Region Arene Dioxides of Pyrene and Dibenz[a, h]Anthracene [1]" @default.
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- W2049086857 doi "https://doi.org/10.1080/10406639908020559" @default.
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