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- W2049102334 abstract "Abstract The luminescence characteristics of tris(2,2 ′ -bipyridine)ruthenium(II) ([Ru(bpy) 3 ] 2+ ) adsorbed on a mesoporous silica was investigated. The adsorption of the complex cation into the mesoporous silica was conducted by the reaction using a dimethylformamide solution of [Ru(bpy) 3 ] 2+ chloride hexahydrate. The amount of adsorbed [Ru(bpy) 3 ] 2+ was controlled by changing the concentration of the solution. When the samples were dehydrated, the adsorbed [Ru(bpy) 3 ] 2+ ions aggregated to cause self-quenching of the luminescence. The luminescence was intensified dramatically upon hydration of the samples, indicating that the aggregated [Ru(bpy) 3 ] 2+ ions were dispersed in the mesopore to suppress the self-quenching. The luminescence characteristics of the adsorbed [Ru(bpy) 3 ] 2+ significantly changed upon washing, showing the possible role of the co-adsorbed Cl − ions." @default.
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- W2049102334 date "2001-11-01" @default.
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- W2049102334 title "Incorporation of tris(2,2′-bipyridine)ruthenium(II) cations ([Ru(bpy)3]2+) into a mesoporous silica" @default.
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