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- W2049108902 abstract "Molecules of 2-amino-4-methoxy-6-methylpyrimidine, C(6)H(9)N(3)O, (I), lie on mirror planes in space group Pnma and are linked by two N-H...N hydrogen bonds [H...N = 2.26 and 2.34 A, N...N = 3.136 (2) and 3.212 (2) A, and N-H...N = 175 and 172 degrees ] into chains of edge-fused R(2)(2)(8) rings, which themselves are linked into sheets by aromatic pi-pi-stacking interactions. In 2-benzylamino-4-benzyloxy-6-methylpyrimidine, C(19)H(19)N(3)O, (II), and 4-benzylamino-2,6-bis(benzyloxy)pyrimidine, C(25)H(23)N(3)O(2), (III), the molecules are linked by paired N-H.N hydrogen bonds [H...N = 2.16 A, N.N = 3.039 (2) A and N-H...N = 165 degrees in (II); H...N = 2.15 A, N...N = 2.980 (2) A and N-H...N = 176 degrees in (III)] into centrosymmetric R(2)(2)(8) dimers, with no direction-specific interactions between these dimeric units." @default.
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- W2049108902 date "2002-12-10" @default.
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- W2049108902 title "Hydrogen bonding in 2-amino-4-methoxy-6-methylpyrimidine, 2-benzylamino-4-benzyloxy-6-methylpyrimidine and 4-benzylamino-2,6-bis(benzyloxy)pyrimidine: π-stacked chains of fused<i>R</i><sub>2</sub><sup>2</sup>(8) rings, and centrosymmetric<i>R</i><sub>2</sub><sup>2</sup>(8) dimers" @default.
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- W2049108902 doi "https://doi.org/10.1107/s0108270102020206" @default.
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