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• W2049113350 endingPage "5689" @default.
• W2049113350 startingPage "5675" @default.
• W2049113350 abstract "The reactions between several derivatives of 1-(3,5-dimethoxyphenyl)-prop-2-yn-1-ol and different ruthenium starting materials [i.e., RuCl2(PPh3)3 and RuCl2(p-cymene)(L), where L is tricyclohexylphosphine di-t-butylmethylphosphine, dicyclohexylphenylphosphine, triisobutylphosphine, triisopropylphosphine, or tri-n-propylphosphine] are described. Several of these reactions allow for the easy, in-situ and atom-economic preparation of olefin metathesis catalysts. Organic precursor 1-(3,5-dimethoxyphenyl)-1-phenyl-prop-2-yn-1-ol led to the formation of active ruthenium indenylidene-ether complexes, while 1-(3,5-dimethoxyphenyl)-prop-2-yn-1-ol and 1-(3,5-dimethoxyphenyl)-1-methyl-prop-2-yn-1-ol did not. It was also found that a bulky and strong σ-donor phosphine ligand was required to impart good catalytic activity to the new ruthenium complexes." @default.
• W2049113350 created "2016-06-24" @default.
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• W2049113350 date "2012-05-11" @default.
• W2049113350 modified "2023-10-07" @default.
• W2049113350 title "Development of a Method for the Preparation of Ruthenium Indenylidene-Ether Olefin Metathesis Catalysts" @default.
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• W2049113350 doi "https://doi.org/10.3390/molecules17055675" @default.
• W2049113350 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3383788" @default.
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