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- W2049118766 abstract "The oxidation of p-ferf-butyltoluene (PTBT) by cobalt (II) acetate in acetic acid has been studied kinetically under mild conditions. Under atmospheric pressure, it was found that the oxidation was a first-order reaction with regard to substrate concentration. A 89% yield to p-ferf-butylbenzoic acid (PTBA) was achieved under normal pressure at 90°C. The oxidation reaction of PTBT under high pressure (0.6 MPa) was also studied and PTBT was oxidized to PTBA in good yields (95%). The industrial process of oxidizing PTBT to PTBA by molecular oxygen containing cobalt acetate catalyst and sodium bromide without solvent was investigated with a view to developing an industrial process for the production of PTBA. A 71.0% yield of PTBA can be obtained at 130°C for 8 h with promising commercial prospects. The mechanism of oxidizing PTBT to PTBA was presented to clarify the reaction procession of PTBT." @default.
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- W2049118766 date "2003-09-01" @default.
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- W2049118766 title "Studies on Catalytic Oxidation of p-Tert-Butyltoluene" @default.
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- W2049118766 doi "https://doi.org/10.1205/026387603322482275" @default.
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